SPM Application in Polymer Material.ppt


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文档列表 文档介绍
Phase Separation Structure
・ABS resin
・PC/AES alloy
・PC/ABS alloy
・ABS/PVC alloy
etc
Lamella Structure
・LD-, MD-, HD- Polyethylene
・Linear LD Polyethylene
・UH Molecular Weight PE
・Polypropylene
etc
Next Generation
・Conducting Polymer
・Organic EL
・Biodegradable Polymer
etc
Micro PSS
Thermoplastic Elastomer
・Styrene Butadiene-
・Polyester-
・Polyvinyl Chloride-
etc
SPM Application in Polymer Material
Structure
Function
Heating/Cooling SPM
●Observation in the heating process with the air
●Surface and Interface Information
●Observation in the inert gas
●Difficult sample for TEM(Rubber/Rubber blend)
Structure and Function of Polymer
ー Morphology observation with SPM ー
Visco-elasticity
Friction Force
Adhesive Force
Glass trans.
Phase
Hardness
Polymer characterization in nano scale level
VE-AFM/DFM
FFM/LM-FFM
PM
Adhesion
Material Characterization using SPM
【Purpose】
◆ Distribution of the characteristics change in the polymer surface can be observed.
【Principle】
◆Detecting the phase change in DFM measurement
【Advantage】
◆Simultaneous imaging with DFM
◆Same advantage as DFM for the soft or charged surface.
(which is difficult to apply LM-FFM or VE-AFM)
resin
silicon rubber
Topography(7μm)
PM image(7μm)
Material Characterization
DFM/PM (Phase mode)measurement
Observed image of the
heat shrinkage rubber
(resin/silicon rubber) →
100 nm
100 nm
Topography
PM image
PP (matrix)
EPR
●Lamella structure can be observed clearly with PM mode.
●Domain of Ethylene Propylene Rubber (EPR) is distributed in the Polypropylene (PP) matrix.
( SPA-300HV, Environment Control Type Unit)
Data Lamella structure of Polypropylene
Phase(PM:Phase Mode)measurement
- Structure and Function of Polymer -
Data Micro Phase Separation Structure of SBS (Phase Mode)
200 nm
.
200 nm
90℃
200 nm
. after cooling
●Polystyrene phase (hard segment) and Polybutadiene phase (soft segment) is clearly separated
●The initial data indicates non-equilibri

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  • 时间2011-09-01