#SupplementaryMaterial(ESI)munications#Thisjournalis©TheRoyalSocietyofChemistry2004ElectronicSupplementaryInformation(ESI)B407771GTheFirstOligopeptideDerivativeof1'-Aminoferrocene-1-carboxylicacidShowsHelicalChiralitywithAntiparallelStrandsLidijaBarisic[a],MajaDropucic[a],VladimirRapic[a],*,HansPritzkow[b],[c],NilsMetzler-Nolte[c],*[a] ,,,HR-10000Zagreb(Croatia)Fax:++385-(0)1-4836082E-mail:******@[b] anisch-ChemischesInstitutderUniversitätHeidelbergImNeuenheimerFeld270,D-69120Heidelberg(Germany)[c] ,-NolteInstitutfürPharmazieundMolekulareBiotechnologieUniversitätHeidelbergImNeuenheimerFeld364,D-69120Heidelberg(Germany)Fax:++49-(0)6221-546441E-mail:-******@-:Fca-Ala-Ala-OMe•HClAsuspensionofBoc-Fca-Ala-Ala-OMe(420mg,)inethylacetate(30ml)wascooledto0º,mixturewasevaporatedinvacuotodrynesstoleaveyellowsolid(304mg,96%)..=-º-Ala-Fca-Ala-Ala-OMe(5)Fca-Ala-Ala-OMe•HCl(145mg,)3/CH2Cl2(pH~8)andcoupledwithBoc-Ala-OH(139mg,)bystandardEDC/,thereactionmixturewaswashedtwicewithasaturatedsolutionofNaHCO3,10%aqueoussolutionofcitricacidandH2O
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