SynthesisandCharacterizationofNovelChiralConjugatedMaterials -----,theinherentthree-dimensionalcharacterofchiralityandthecontrolofintermolecularinteractionsassociatedwithdiastereomericrecognitionprovideaversatilehandlefortheoptimizationofsupramolecularstructures,filmmorphologyandliquidcrystallineorderofp-(circularpolarizationoflight),electronics(chiraltransportofchargecarriers),,,approachingorexceedinginmagnitudetheirachiralcounterparts,-conjugatedsystems,withthefocusonhelicene-,configurationalstability(barriersforracemization)- [n]Helicenespossessangularlyannelatedaromaticrings,formingahelicallyshapedp-conjugatedsystem,suchassixortho-annelatedbenzeneringsin[6]helicene(1)’sgroupadoptedthecobalt--photochemi
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