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学位论文原创性声明本人郑重声明:所呈交的论文是本人在导师的指导下独立进行研究所取得的研究成果。除了文中特别加以标注引用的内容外,本论文不包含任何其他个人或集体已经发表或撰写的成果作品。: 201 2年5月20日学位论文版权使用授权书本学位论文作者完全了解学校有关保障、使用学位论文的规定,同意学校保留并向有关学位论文管理部门或机构送交论文的复印件和电子版,允许论文被查阅和借阅。本人授权省级优秀学士学位论文评选机构将本学位论文的全部或部分内容编入有关数据库进行检索,可以采用影印、缩印或扫描等复制手段保存和汇编本学位论文。本学位论文属于 □,在_________ 年解密后适用本授权书。 □。(请在以上相应方框内打“√”)作者签名: 201 2年月日导师签名: 年月日目录摘要····················································································· (1) 前言····················································································· (1) 正文····················································································· (3) 1 选题背景······································································ (4) 课题来源································································· (4) 研究的目的和意义····················································· (4) 研究进展································································· (4) 展望······································································· (6) 2 实验部分···································································· (6) 实验仪器及试剂························································· (6) 实验步骤·································································· (7) 3. 结果与讨论···································································· (8) 红外光谱分析···························································· (8) 电化学分析····························································· ( 10) ··········································································· (12) 致谢··················································································· ( 13) 参考文献············································································· ( 14) 没食子酸酯金属配合物研究学生: 向玖林指导老师:代忠旭三峡大学化学与生命科学学院化学系摘要:本文主要利用循环伏安法研究了没食子酸异戊酯金属铜络合物的电化学性质,并运用红外光谱对络合物的结构进行了分析。红外光谱表明金属离子与酚羟基发生了配位。循环伏安研究结果表明,金属配位后,共轭体系增大,电子云密度降低,整个分子中电子离域程度更大,较易失去电子,因而具有较高的氧化还原活性。关键词:没食子酸异戊酯金属铜络合物;循环伏安法;红外光谱 Study on plex with I

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