经检索《Web of Science》2009年,以广西民族大学(Guangxi Univ Nationalities)为作者单位发表论文被《Sci》核心版收录32篇(检索时间2018/1/6)。
Record 1 of 32
Author(s): Hu, FL (Hu, Feilong); Yin, XH (Yin, Xianhong); Mi, Y (Mi, Yan); Zhang, SS (Zhang, Shanshan); Luo, WQ (Luo, Weiqiang); Zhuang, Y (Zhuang, Yue)
Title: Synthesis, structure, and properties of two novel copper(II) complexes, [Cu(phen)(L)(2)]center dot 6H(2)O and [Cu(phen)(3)]center dot(ClO4)(2)
Source: ANIC MUNICATIONS, 12 (12): 1189-1192 DEC 2009
Language: English
Document Type: Article
Author Keywords: Copper(II) complex; Water clusters; Anion exchange; Crystal structure
KeyWords Plus: T4(2)6(2) WATER TAPE; (H2O)(10) CLUSTER; PLEX; COORDINATION POLYMERS; SOLID-STATE; ANION-EXCHANGE; AB-INITIO; FRAMEWORK; NETWORK; CADMIUM(II)
Abstract: Two novel copper(II) complexes, namely [Cu(phen)(L)(2)]center dot 6H(2)O (1) and [Cu(phen)(3)]center dot(ClO4)(2) (2) have been synthesized under mild condition (HL = 5-methyl-1H-pyrazole-3-carboxylic acid, phen = 1,10-phenanthroline). We report the structural evidence of discrete water clecamer conformation in the solid state. These units are found to act as supramolecular glue in the aggregation of mononuclear copper(II) complex to give a three-work through hydrogen-bonding. The preliminary investigation on the thermal behavior and the anion exchange property of plexes are presented. Crown Copyright (C) 2009 Published by Elsevier . All rights reserved.
Addresses: [Hu, Feilong; Yin, Xianhong; Mi, Yan; Zhang, Shanshan; Luo, Weiqiang; Zhuang, Yue] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 530006, Peoples R China
Reprint Address: Yin, XH, Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 530006, Peoples R China.
E-mail Address: yxhphd@
Funding Acknowledgement:
Funding Agency
Grant Number
National Natural Science Foundation of China, PR China
(20761002)
Natural Science Foundation of Guangxi
0832080
PR China and Innovation Project of Guangxi' University
gxun-chx20
Synthesis, structure, and properties of two novel copper (II) complexes,[Cu (phen)(L)(2)] center dot 6H (2) O and [Cu (phen)(3)] center dot (ClO4)(2) 来自淘豆网m.daumloan.com转载请标明出处.
